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ST0880 Tantalum doped Lithium Lanthanum Zirconate Sputtering Target

Chemical Formula: Ta-doped LLZO
Catalog Number: ST0880
Purity: 99.9% ~ 99.999%
Shape: Discs, Plates, Column Targets, Step Targets, Custom-made

Tantalum-Doped Lithium Lanthanum Zirconate sputtering target  come in various forms, purities, sizes, and prices. Thin Film Materials (TFM) manufactures and supplies top-quality sputtering targets at competitive prices.

Introduction

The Tantalum Doped Lithium Lanthanum Zirconate Sputtering Target (Ta-LLZO) is a high-performance ceramic target used in thin film deposition for solid-state battery technologies and advanced energy storage systems. Tantalum-doped lithium lanthanum zirconate is a garnet-type solid electrolyte known for its high lithium-ion conductivity, excellent chemical stability, and compatibility with lithium metal anodes.

Using magnetron sputtering or other physical vapor deposition (PVD) techniques, Ta-LLZO sputtering targets enable the deposition of dense, uniform thin films suitable for solid-state lithium batteries, micro-batteries, and advanced electrochemical devices. These materials are widely studied for next-generation energy storage solutions due to their improved safety and performance compared with traditional liquid electrolytes.

Detailed Description

Tantalum-doped lithium lanthanum zirconate sputtering targets are typically manufactured from high-purity lithium, lanthanum, zirconium, tantalum, and oxygen compounds through controlled ceramic synthesis processes. Common manufacturing techniques include powder mixing, calcination, and high-temperature sintering or hot pressing to achieve a dense and homogeneous target structure.

The base compound, lithium lanthanum zirconate (Li₇La₃Zr₂O₁₂, commonly known as LLZO), has a garnet-type crystal structure that supports fast lithium-ion transport. Doping the material with tantalum improves the stabilization of the cubic phase of LLZO, which significantly enhances ionic conductivity and electrochemical stability.

Ta-LLZO thin films deposited through sputtering can serve as solid electrolyte layers in thin film batteries and microelectronic energy storage devices. These films provide excellent resistance to dendrite formation and chemical stability when in contact with lithium metal.

High-density sputtering targets help ensure stable sputtering rates and uniform film composition. Depending on the sputtering system requirements, Ta-LLZO targets can be supplied as planar ceramic targets or bonded targets with copper backing plates, improving heat dissipation and mechanical stability during deposition.

Applications

Tantalum-doped lithium lanthanum zirconate sputtering targets are primarily used in advanced energy and electronic technologies:

  • Solid-state lithium batteries using ceramic electrolytes

  • Thin film micro-batteries for microelectronics and MEMS devices

  • Energy storage research focused on next-generation battery materials

  • Electrochemical devices requiring lithium-ion conducting layers

  • Battery interface engineering in solid electrolyte systems

  • Academic and industrial research laboratories studying solid-state battery materials

Technical Parameters

ParameterTypical Value / RangeImportance
Chemical FormulaLi₇La₃Zr₂₋ₓTaₓO₁₂ (Ta-LLZO)Determines ionic conductivity and electrolyte performance
Purity≥ 99.9%Ensures stable electrochemical properties
Diameter25 – 300 mm (custom)Compatible with common sputtering systems
Thickness3 – 6 mmInfluences sputtering stability and target lifetime
Density≥ 95% theoretical densitySupports uniform thin film deposition
BondingCopper backing plate / Indium bondedImproves heat transfer during sputtering

Comparison with Related Materials

MaterialKey AdvantageTypical Application
Ta-LLZOHigh lithium-ion conductivity and dendrite resistanceSolid-state battery electrolytes
LLZO (undoped)Garnet electrolyte structureSolid-state lithium battery research
LiPONStable thin film electrolyteThin film lithium batteries

FAQ

QuestionAnswer
What is the advantage of tantalum doping in LLZO?Tantalum stabilizes the cubic LLZO phase, which significantly improves lithium-ion conductivity and electrochemical stability.
What sputtering methods are suitable for Ta-LLZO targets?RF magnetron sputtering is commonly used for depositing ceramic electrolyte thin films.
Can the target size be customized?Yes. Targets can be manufactured in various diameters, thicknesses, and bonding configurations.
Are bonded sputtering targets available?Yes. Ceramic targets can be bonded to copper backing plates to improve heat dissipation during sputtering.
What substrates are commonly used for Ta-LLZO films?Films can be deposited on silicon wafers, stainless steel substrates, glass, and other battery-compatible materials.

Packaging

Our Tantalum Doped Lithium Lanthanum Zirconate Sputtering Target (Ta-LLZO) products are meticulously tagged and labeled externally to ensure efficient identification and maintain high standards of quality control. Each target is carefully packaged in vacuum-sealed bags with protective foam materials and export-grade cartons or wooden crates to prevent contamination and mechanical damage during storage and transportation.

Conclusion

The Tantalum Doped Lithium Lanthanum Zirconate Sputtering Target (Ta-LLZO) is a critical material for the development of solid-state battery technologies and advanced electrochemical devices. Its high ionic conductivity, chemical stability, and compatibility with lithium metal make it an ideal electrolyte material for next-generation energy storage systems.

With customizable sizes, high-density ceramic manufacturing, and stable sputtering performance, Ta-LLZO sputtering targets support cutting-edge research and industrial development in solid-state battery technology.

For detailed specifications and a quotation, please contact us at sales@thinfilmmaterials.com.

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FAQ

It’s the source material (in solid form) used in sputter deposition to eject atoms or molecules that then form a thin film on a substrate.

Targets can be pure metals (e.g., gold, copper, aluminum), ceramics (e.g., Al₂O₃, SiO₂, TiO₂), alloys, or composites—chosen based on the film’s desired properties.

 

They are produced by processes such as melting/casting for metals or sintering (often with hot isostatic pressing) for ceramics and composite targets to ensure high density and purity.

 

In a vacuum chamber, a plasma (typically argon) bombards the target, ejecting atoms that travel and condense on a substrate, forming a thin film.

 

Key factors include the target’s purity, density, grain structure, and the sputtering yield (i.e. how many atoms are ejected per incident ion), as well as operating conditions like power density and gas pressure.

 

Operators monitor target erosion (often by measuring the depth of the eroded “race track”) or track total energy delivered (kilowatt-hours) until it reaches a threshold that can compromise film quality.

 

Fragile materials (such as many ceramics or certain oxides) and precious metals often require a backing plate to improve cooling, mechanical stability, and to allow thinner targets that reduce material costs.

 

DC sputtering is used for conductive targets, while RF sputtering is necessary for insulating targets (like many oxides) because it prevents charge buildup on the target’s surface.

 

In reactive sputtering, a reactive gas (e.g., oxygen or nitrogen) is introduced to form compound films on the substrate, but it may also “poison” the target surface if not carefully controlled.

 

Many manufacturers prefer to control raw material quality by sourcing their own powders; using external powders can risk impurities and inconsistent target properties.

 

Targets should be stored in clean, dry conditions (often in original packaging or re-wrapped in protective materials) and handled with gloves to avoid contamination, ensuring optimal performance during deposition.

Deposition rate depends on factors such as target material and composition, power density, working gas pressure, substrate distance, and the configuration of the sputtering system (e.g., magnetron design).

 
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